Accession Number:

ADA025197

Title:

Ionization Processes Relevant to the Formation of New Materials.

Descriptive Note:

Final rept. 1 Oct 70-31 Aug 75,

Corporate Author:

WISCONSIN UNIV MADISON DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1975-08-31

Pagination or Media Count:

4.0

Abstract:

This research program involved investigation of the structure and chemistry of intermediates in ionic reactions viz. carbonium ion reactions. The approach has been to determine symmetry properties of product forming intermediates and from these deduce structural details of these intermediates. Kinetic, isotope tracer and stereochemical methods were used. In connection with the latter a new technique was developed which involves the use of optically active nmr shift reagents for the direct determination of enantiomeric compositions. With this technique it was possible to solve problems that could not be handled by other methods. Author

Subject Categories:

  • Organic Chemistry
  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE