Pentacarbonyliron(0) Photocatalyzed Reactions of Trialkylsilanes with Alkenes.
MASSACHUSETTS INST OF TECH CAMBRIDGE DEPT OF CHEMISTRY
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Irradiation of FeCO5 in the presence of R3SiHR CH3- or C2H5- and an alkene leads to the formation of alkane, alkyl-SiR3, and alkenyl-SiR3 in a ratio dependent on temperature and initial substrate ratios. The key species generated by the light is HR3SiFeCO3alkene which can be used to account for all products and their dependence on temperature and substrate ratio. The products can be obtained in synthetic quantities. Author
- Organic Chemistry
- Radiation and Nuclear Chemistry