Comment on 'A Paradox: The Thermal Rate Coefficient for the H + DCl yields HCl + D Exchange Reaction'.
AEROSPACE CORP EL SEGUNDO CALIF AEROPHYSICS LAB
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Experimental data are presented that show that chlorine atom abstraction from HCl by a colliding D or H atom is relatively slow at room temperature. These slow rates are much smaller than those obtained by trajectory calculations, suggesting that the activation energy for this process is 3 kcalmol. Author
- Physical Chemistry