Accession Number:

ADA009240

Title:

Isomeric (eta5-C5H5)NiB9H9 - Metalloborane Anions from B9H12(-) and Nickelocene.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s):

• Leyden,Richard N.
• Hawthorne,M. Frederick

Report Date:

1975-04-18

Pagination or Media Count:

9.0

Abstract:

Reaction of B9H12- and NiC5H52 with NaHg produces the metalloborane eta5-C5H5-2-Nieta5-B9H9- which is quantitatively converted to a second isomer eta5-C5H5-1-Nieta4-B9H9- by thermal isomerization.

Descriptors:

• *BORANES
• *NICKEL COMPOUNDS
• SYNTHESIS(CHEMISTRY)
• ORGANOMETALLIC COMPOUNDS
• MOLECULAR ISOMERISM
• ANIONS
• METAL COMPLEXES

Subject Categories:

• Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE