Free Energy Determinations by Solid Galvanic Cell Measurements for Selected Metal, Metal-Fluoride Reactions.
IOWA STATE UNIV AMES ENGINEERING RESEARCH INST
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Free energies for displacement reactions involving metals and their fluorides have been measured at various temperatures by the solid electrolyte galvanic cell technique. The results are presented in the form of cell emf vs temperature equations. By combining these results with data from the literature, standard free energies of formation data for the fluorides studied have also been calculated and tabulated for use in conventional thermodynamic calculations.
- Physical Chemistry