Accession Number:

ADA001082

Title:

Preparation of B-sigma-Metallocarboranes by Oxidative Addition; Model Intermediates for Transition Metal Catalyzed H-D Exchange in B-H Containing Species.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1974-10-31

Pagination or Media Count:

12.0

Abstract:

A number of B-sigma-metallocarboranes have been prepared by oxidative addition of carboranyl boron-hydrogen bonds to an iridium complex. The complexes are models for intermediates in the transition metal catalyzed exchange of deuterium gas for hydrogen at terminal B-H bonds, and do themselves actively catalyze such exchange. Spectra are reported for 3-PPh32Ir HCl-1,2-C2B10H11.

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE