Accession Number:

ADA000959

Title:

Disproportionation-Combination Ratios in Thermalized Cyclic Radical Systems. Rate of Isomerization of Pent-2-en-5-yl Radical.

Descriptive Note:

Technical rept.,

Corporate Author:

WASHINGTON UNIV SEATTLE DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1974-10-30

Pagination or Media Count:

10.0

Abstract:

Disproportionation-combination rate ratios have been measured for a number of pairs of thermalized radicals 298K generated by thermalization of chemically activated cycloalkyl radicals, their ring-opened products and ethyl radicals. These ratios are reported and briefly discussed. The rate of isomerization of chemically activated pent-2-en-5-yl radical via H-atom transfer to the allylic pent-1-en-3-yl radical is also given.

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE