Accession Number:

ADA000669

Title:

Mechanism of the Catalytic Oxidation of Olefins (Mekhanizm i Kinetika Geterogennykh Reaktsii),

Descriptive Note:

Corporate Author:

FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO

Personal Author(s):

Report Date:

1974-10-30

Pagination or Media Count:

21.0

Abstract:

The use of diverse methods as kinetic, adsorptive, electrical and isotopic enabled the author to propose a stepwise diagram of the oxidation of olefin hydrocarbons on different oxidizing catalysts. Propylene on the surface can form pi-complexes, or after dissociation, pi-allyl complexes. Both forms are converted into different oxygen-hydrocarbon complexes with interaction with oxygen Studies of the chemisorption of the reaction components under the conditions of pre-catalysis the adsorption temperature is lower than the temperature of the start of the reaction and research on the behavior of the different oxygen-containing products on the catalyst surface area using kinetic and isotopic methods were undertaken for proof of the existence of such forms.

Subject Categories:

  • Organic Chemistry
  • Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE