Accession Number:

ADA000529

Title:

Structural Studies of Dibenz(c,f)Azocines. II. N-t-Butyl-5,6-Dihydro-7H,12H-Dibenz(c,f)Azocine,

Descriptive Note:

Corporate Author:

NATIONAL RESEARCH COUNCIL OF CANADA OTTAWA (ONTARIO) DIV OF BIOLOGICAL SCIENCES

Personal Author(s):

Report Date:

1974-03-08

Pagination or Media Count:

5.0

Abstract:

Crystals of the title compound, C19H23N, are triclinic. The crystal structure has been determined by the symbolic addition procedure and refined by the least-squares method to R0.052 for the 1993 observed reflections. The azocine ring has the twist-boat conformation with half of the molecules left-handed and the other half right-handed, but otherwise the same degree of twist for all molecules. The length of the N...C diagonal is 2.86 A, indicating very weak transannular interaction across the azocine ring. Some preferred localization of electronic charge is observed in the benzene rings. Structure is reported. Modified author abstract

Subject Categories:

  • Organic Chemistry
  • Crystallography

Distribution Statement:

APPROVED FOR PUBLIC RELEASE