Accession Number:

AD1061218

Title:

Mechanisms for Catalytically Abating Organosulfur Compounds with H2O2 Formed In Situ

Descriptive Note:

Technical Report,15 Apr 2016,14 Apr 2017

Corporate Author:

University of Illinois - Urbana - Champaign Champaign United States

Personal Author(s):

Report Date:

2018-04-19

Pagination or Media Count:

10.0

Abstract:

We will synthesize a variety of supported metal-oxide catalysts e.g., V, Nb, Ta to study the formation and reaction of M-OOH moieties with organic reactants to determine the rates, selectivity, and mechanism for small molecule oxidation. We will synthesize a series of similarly structured metal-oxide catalysts by depositing low loadings 0.2 - 3 wt. of V, Nb, Ta, Ti, etc. precursors onto silica by SEA and into zeolite frameworks by treating zeolite with moderate aluminum content e.g., SiAl 25 with strong HNO3 solutions followed by metal-ion exchange.

Subject Categories:

  • Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE