Accession Number:

AD1020452

Title:

Intramolecular Charge Transfer of Conjugated Liquid Crystal Ferrocene Macromolecules - Synthesis and Characterization

Descriptive Note:

Technical Report,15 Aug 2014,14 Jan 2016

Corporate Author:

CIQA Saltillo Mexico

Personal Author(s):

• Ziolo,Ronald

Report Date:

2016-04-12

Pagination or Media Count:

18.0

Abstract:

The design, synthesis and characterization of a new series of conjugated macromolecules bearing ferrocene as a highly efficient electron donor material coupled to 2,5-dialcoxy benzene ethynylenes as a pi-conjugated connector and benzoate or phenyl carboxylic acid as termini and electron attractor groups to create a push-pull effect with efficient charge transfer, D-pi-A, are reported. The rigid, rod-like phenyleneethynylene chain bears flexible dodecanoxy group chains to impart liquid crystal properties.

Descriptors:

• liquid crystals
• absorption
• Chromophores
• Ferrocenes
• charge transfer
• macromolecules
• two photon absorption
• chromatography

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE