Intramolecular Charge Transfer of Conjugated Liquid Crystal Ferrocene Macromolecules - Synthesis and Characterization
Technical Report,15 Aug 2014,14 Jan 2016
CIQA Saltillo Mexico
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The design, synthesis and characterization of a new series of conjugated macromolecules bearing ferrocene as a highly efficient electron donor material coupled to 2,5-dialcoxy benzene ethynylenes as a pi-conjugated connector and benzoate or phenyl carboxylic acid as termini and electron attractor groups to create a push-pull effect with efficient charge transfer, D-pi-A, are reported. The rigid, rod-like phenyleneethynylene chain bears flexible dodecanoxy group chains to impart liquid crystal properties.