Accession Number:

AD1014955

Title:

Heme-Containing Metal-Organic Frameworks for the Oxidative Degradation of Chemical Warfare Agents

Descriptive Note:

Technical Report,15 Apr 2015,14 Jan 2016

Corporate Author:

Northwestern University Evanston Campus Evanston United States

Report Date:

2016-04-14

Pagination or Media Count:

10.0

Abstract:

This project sought to employ heme-containing metal-organic framework MOF materials to carry out the oxidative degradation of small molecules that serve as models of chemical warfare agents. Both gas- and solution phase experiments were be pursued, using oxidants such as molecular O-atom transfer agents and gaseous dioxygen. These initial studies included characterization of the first porphyrin ironIV oxo species within a MOF and the first example of a ironI porphyrin within a MOF.

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE