Accession Number:

AD0831845

Title:

PROBLEMS RELATING TO AMIDO-DERIVATIVES OF METALS AND METALLOIDS. VOLUME II. THE CHEMISTRY OF AMIDO-DERIVATIVES OF TITANIUM, ZIRCONIUM, AND HAFNIUM.

Descriptive Note:

Final technical rept. Oct 66-Sep 67,

Corporate Author:

SUSSEX UNIV BRIGHTON (UNITED KINGDOM) CHEMICAL LAB

Personal Author(s):

• Cardin, D. J.
• Chandra, G.
• Lappert, M. F.

Report Date:

1967-11-01

Pagination or Media Count:

269.0

Abstract:

The chemistry of amido-derivatives of titanium, zirconium and hafnium of the type MNR24, where R Me or Et, was studied. The various reactions of these amido derivatives that were explored may be classified as follows 1 reactions with active-hydrogen compounds 2 insertion reactions 3 amination reactions 4 polymerization reactions and, 5 miscellaneous reactions. New derivatives were characterized by elemental analysis, nuclear magnetic resonance spectroscopy, and mass spectroscopy. Author

Descriptors:

• *ORGANOMETALLIC COMPOUNDS
• *AMIDES
• TITANIUM COMPOUNDS
• ZIRCONIUM COMPOUNDS
• HAFNIUM COMPOUNDS
• SYNTHESIS(CHEMISTRY)
• POLYMERIZATION
• CHEMICAL REACTIONS
• INFRARED SPECTROSCOPY
• RAMAN SPECTROSCOPY
• NUCLEAR MAGNETIC RESONANCE
• MASS SPECTROSCOPY
• CATALYSTS

Subject Categories:

• Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE