ORGANOMETALLIC RESEARCH PROGRAM.
Rept. no. 3 (Final), Jul 65-Jun 67,
NAVAL WEAPONS CENTER CORONA LABS CA
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In beryllium-phosphorus chemistry, BeOPR2O2x polymers were prepared, where R CH3, n-C4H9, n-C5H11, n-C7H15, C6H5, or C6F5 R2 CH24 or CH3 and C6H5. The thermal characteristics of these polymers were studied by DTAs and TGAs. The dimer CH3COCHCOCH3BeOPC6H5CB10H10CCH302 was also prepared. In boron chemistry, Be and Zn acetylacetonates were treated with o-carborane carboxylic acids and bis-hydroxymethyl-o-carborane, and Be acetylacetonate was treated with decarborane complexes. Several attempts were made to substitute a Be for a B atom in the C2B10H10 cage of o-CH3CCHB10H10. Author
- Polymer Chemistry