Accession Number:

AD0783937

Title:

19F Chemical Shifts and Infrared C-F Stretching Frequencies for Bridgehead Fluorides.

Descriptive Note:

Technical rept.,

Corporate Author:

MORRIS BROWN COLL ATLANTA GA DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1974-08-05

Pagination or Media Count:

22.0

Abstract:

Several 3-substituted-1-fluoroadamantanes and 4-substituted-1-fluorobicyclo 2.2.2 octanes have been synthesized. The 19F chemical shifts and C-F stretching frequencies for these bridgehead fluorides have been measured. The 19F substituent chemical shifts SCS extended the previously reported correlation of anomalous substituent effects on 19F chemical shifts of bridgehead fluorides. These 19F chemical shifts are incompatible with both theoretical and experimental explanations for proton chemical shifts, where comparable. The C-F stretching frequencies shifts SFS are anomalous when compared to the corresponding C-H data. Limited experimental data preclude a meaningful explanation at this time. Author

Subject Categories:

  • Organic Chemistry
  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE