Electrochemical Processes Associated with Energy Transfer.
Final scientific rept.,
NORTH CAROLINA UNIV CHAPEL HILL DEPT OF CHEMISTRY
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The reported project has had as its main theme study, on a broad front of research, the modes of energy transfer which can accompany electrochemically induced charge-transfer process. Significant aspects of electrochemical techniques, theory, instrumentation, developed during our studies of energy transfer modes have been 1 development of a computer controlled rapid scan stop flow kinetic spectrometer, 2 determination, using this spectrometer, of the kinetics and mechanism of an important and common electrochemical reaction sub-component, the protonation of a radical anion, 3 development of the theory for half-order regeneration reactions, a difficult-to-assess but perhaps common type of anodic electrode process, and 4 description of a new form of metal complex adsorption involving formation of adsorbed two-dimensional crystal phases. Modified author abstract
- Physical Chemistry