Accession Number:

AD0777974

Title:

New 13-Atom Bimetallocarboranes Prepared by Polyhedral Subrogation.

Descriptive Note:

Interim rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s):

• Dustin,Donald F.
• Hawthorne,M. Frederick

Report Date:

1974-04-09

Pagination or Media Count:

36.0

Abstract:

The reaction of 13-vertex cobaltacarbonanes, eta-C5H5-CoC2B10H12, with ethanolic postassium hydroxide in the presence of cyclopentadiene and an appropriate metal salt produces new 13-vertex bimetallllocarboranes. These bimetallic products, which may contain identical or dissimilar metals, have one less boron atom than does the original monometallocarborane. The preparation, characterization and structures of these complexes are discussed. Author

Descriptors:

• *CARBORANES
• *COBALT COMPOUNDS
• *IRON COMPOUNDS
• ELECTROCHEMISTRY
• MASS SPECTRA
• MOLECULAR STRUCTURE
• SYNTHESIS(CHEMISTRY)
• ORGANOMETALLIC COMPOUNDS
• NUCLEAR MAGNETIC RESONANCE
• ULTRAVIOLET SPECTRA
• VISIBLE SPECTRA

Subject Categories:

• Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE