Accession Number:

AD0777674

Title:

The Crystal and Molecular Structure of a Novel Bimetallocarborane Anion.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s):

• Evrard,Guy
• Ricci,John A. , Jr.
• Bernal,Ivan
• Evans,William J.
• Dustin,Donald F.

Report Date:

1974-02-21

Pagination or Media Count:

11.0

Abstract:

The bimetallocarborane, C2H54Neta-C5H5-Co-C2B8H10-Co-C2B8H10, which was prepared by the polyhedral expansion of 1,6-C2B8H10 at -80 degrees, was studied by single crystal diffraction techniques and NMR. Molecular and crystal structure are discussed.

Descriptors:

• *CARBORANES
• *COBALT COMPOUNDS
• ORGANOMETALLIC COMPOUNDS
• SYNTHESIS(CHEMISTRY)
• CRYSTAL STRUCTURE
• X RAY DIFFRACTION
• SINGLE CRYSTALS
• MOLECULAR STRUCTURE
• NUCLEAR MAGNETIC RESONANCE
• ANIONS
• BORATES

Subject Categories:

• Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE