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The Thermal Rearrangements of Non-Ichosahedral Cobaltacarboranes.
CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY
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The thermal rearrangements which isomerize the known isomers of non-icosahedral cobaltacarboranes of the type eta-C5H5CoC2BnHn2, n 6, 7, 8, and 10, are discussed. A summary of conclusions regarding these rearrangements is presented as a set of empirical rules which seem to govern the migration of heteroatoms during thermal isomerizations. Kinetic data of some representative rearrangements are also discussed. Author
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