Accession Number:

AD0776277

Title:

The Thermal Rearrangements of Non-Ichosahedral Cobaltacarboranes.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s):

• Dustin,Donald F.
• Evans,William J.
• Jones,Christopher J.
• Wiersema,Richard J.
• Gong,Henry

Report Date:

1974-02-21

Pagination or Media Count:

36.0

Abstract:

The thermal rearrangements which isomerize the known isomers of non-icosahedral cobaltacarboranes of the type eta-C5H5CoC2BnHn2, n 6, 7, 8, and 10, are discussed. A summary of conclusions regarding these rearrangements is presented as a set of empirical rules which seem to govern the migration of heteroatoms during thermal isomerizations. Kinetic data of some representative rearrangements are also discussed. Author

Descriptors:

• *CARBORANES
• *MOLECULAR ISOMERISM
• REACTION KINETICS
• COBALT COMPOUNDS
• ORGANOMETALLIC COMPOUNDS

Subject Categories:

• Inorganic Chemistry
• Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE