Accession Number:

AD0773942

Title:

High Energy Halogen Chemistry.

Descriptive Note:

Annual rept. 1 Dec 72-1 Dec 73,

Corporate Author:

FLUOROCHEM INC AZUSA CALIF

Report Date:

1974-01-01

Pagination or Media Count:

102.0

Abstract:

The reaction of primary alkyl iodides with silver perchlorate gave mainly rearranged perchlorates in hydrocarbon or halocarbon solvents but unrearranged products in benzene. Silver triflate gave similar results. Alkyl iodides and dichlorine heptoxide gave alkyl perchlorates and an unidentified material that converted additional alkyl iodide to ether. Alkyl hypochlorites and iodine gave hypoiodites. Halogens and interhalogens reacted with olegins in the presence of dichlorine heptoxide or silver perchlorate to give beta-halo perchlorates. Reactions of alcohols, amines and ethers with dichlorine heptoxide are described. Author

Subject Categories:

  • Inorganic Chemistry
  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE