Failure of Intramolecular Reaction Systems.
WASHINGTON UNIV SEATTLE DEPT OF CHEMISTRY
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Singlet methylene free radicals were used to chemically activate a series of alkyl fluorocyclopropanes with alkyl side chain of increasing size, CF3, C3F7, C5F11. Failure of intramolecular energy randomization on a short time scale is demonstrated and the internal relaxation time is given. Modified author abstract
- Organic Chemistry