Accession Number:

AD0773557

Title:

Failure of Intramolecular Reaction Systems.

Descriptive Note:

Technical rept.,

Corporate Author:

WASHINGTON UNIV SEATTLE DEPT OF CHEMISTRY

Report Date:

1974-01-21

Pagination or Media Count:

10.0

Abstract:

Singlet methylene free radicals were used to chemically activate a series of alkyl fluorocyclopropanes with alkyl side chain of increasing size, CF3, C3F7, C5F11. Failure of intramolecular energy randomization on a short time scale is demonstrated and the internal relaxation time is given. Modified author abstract

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE