Polyhedral Expansion of Metallocarboranes.
CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY
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New metallocarboranes of general formula C5H52Co2C2BnHn2 and C5H53Co3C2BnHn2 can be directly prepared by the reduction of the closo monometallodeca-, undeca-, and dodecaboranes with Na in the presence of naphthalene followed by addition of CoCl2 and NaC5H5. The preparation, characterization and proposed structures of these metallocarboranes are discussed. Modified author abstract
- Inorganic Chemistry
- Organic Chemistry