Accession Number:

AD0770156

Title:

Inorganic Coordination Polymers. XV. Dioctylphosphinates of Chromium(II), Manganese(II), Iron(II), Nickel(II), and Copper(II).

Descriptive Note:

Technical rept.,

Corporate Author:

PENNWALT CORP KING OF PRUSSIA PA RESEARCH AND DEVELOPMENT DEPT

Personal Author(s):

Report Date:

1973-11-01

Pagination or Media Count:

22.0

Abstract:

The dioctylphosphinates MrOPC8H172O2, where M divalent Cr, Mn, Fe, Ni, and Cu, have been prepared and characterized. In the solid state all appear to have octahedral or square planar coordination around the metal. The nickel derivative converts to a tetrahedral form above its melting point, whereas the copper and manganese derivatives change geometry upon dissolution. The infrared spectra of these materials in the PO2 stretching region suggest that several different types of metal phosphinate coordinate linkages are present. Modified author abstract

Subject Categories:

  • Inorganic Chemistry
  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE