A Fluorine-19 NMR Study of Some Fluorotitanium(IV) Complexes. III.
Final technical rept. 16 Jan 72-15 Jan 73,
WITTENBERG UNIV SPRINGFIELD OHIO
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The stereochemistry of a number of titanium IV fluoride complexes has been studied by means of low temperature fluorine-19 nmr. The following systems are examined in this technical report TiF4--TiBr4--2,6-Dimethylpyridine-N-oxide TiF4--TiCl4--Dioxane TiF4--TiCl4--Thioxane TiF4--TiCl4--Dithiane TiF4--H2O--Chloroacetonitrile TiF4--H2O--Methylal TiF4--TiCl4--H2O--1,2-Dimethoxyethane TiF4--TiBr4--H2O--1,2-Dimethoxyethane Structural assignments as well as chemical shift and coupling constant data are presented for each observed complex. In the systems involving water, species containing hydroxyl groups could not be detected although hydrolysis was clearly indicated by the formation of a white precipitate. Author
- Inorganic Chemistry