Accession Number:

AD0766071

Title:

Electronic Considerations in Metalloboranes.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Report Date:

1973-06-13

Pagination or Media Count:

9.0

Abstract:

A 2n 14 electron rule is proposed for closo n-vertex polyhedral heteroboranes containing one transition metal vertex. Nido polyhedra of this type require 2n 16 electrons while closo polyhedra with two transition metal vertices require 2n 26 electrons. The application and chemical consequences of these proposals are discussed. Author

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE