Accession Number:

AD0763481

Title:

The Synthesis of a Mixed-Metal, Bimetallic, Monocarbon Metallocarborane by Polyhedral Expansion.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Report Date:

1973-06-14

Pagination or Media Count:

11.0

Abstract:

Addition of NaC5H5- and NiBr22C2H4OCH32 to CH34Npi-C5H5CoIII-pi-CB7H8 previously reduced with sodium naphthalide formed a new bimetallic mixed-metal monocarbon metallocarborane pi-C5H5CoIIIpi-CB7H8NiIVpi-C5H5, isolated in at least four isomeric forms. This represents a new extension of the polyhedral expansion reaction to monocarbon metallocarboranes. Author

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE