The Synthesis of a Mixed-Metal, Bimetallic, Monocarbon Metallocarborane by Polyhedral Expansion.
CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY
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Addition of NaC5H5- and NiBr22C2H4OCH32 to CH34Npi-C5H5CoIII-pi-CB7H8 previously reduced with sodium naphthalide formed a new bimetallic mixed-metal monocarbon metallocarborane pi-C5H5CoIIIpi-CB7H8NiIVpi-C5H5, isolated in at least four isomeric forms. This represents a new extension of the polyhedral expansion reaction to monocarbon metallocarboranes. Author
- Organic Chemistry