Accession Number:

AD0756216

Title:

A Novel Transfer of the Diazonium Function from Carbon to Boron.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Report Date:

1973-02-07

Pagination or Media Count:

8.0

Abstract:

Coupling B10H102- with 2,4,6-tribromobenzene diazonium ion produced a protonated azo compound with the azo function in an apical polyhedral position. When this product heated at reflux in acetonitrile for three hours, 1-B10H9N2- and 1,3,5-tribromobenzene are formed in good yield. This method provides the only known route to mono diazonium substituted B10H102-0 and in addition it may be extended to other B10H102- derivatives. Author

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE