Accession Number:

AD0755466

Title:

Intramolecular Oxidative Addition of Iridium to a Boron-Hydrogen Bond of a Complexed Carboranyl Phosphine.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Report Date:

1972-01-03

Pagination or Media Count:

8.0

Abstract:

When IrC8H142Cl2 is allowed to react at room temperature with 6 moles of 1-Me2P-1,2-C2B10H11 in cyclohexane and then heated at reflux for two hours, IrHClC2B10H10PCH32CH32C2B10H11PCH322 is formed in nearly quantitative yield. This is the first example of intramolecular oxidative addition of an ortho B-H bond of a coordinated phosphine to a transition metal. Author

Subject Categories:

  • Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE