Crystal and Molecular Structure of N-p-Bromobenzoyl-exo-2,3-aziridinobicyclo(2,2,1)heptane,
NATIONAL RESEARCH COUNCIL OF CANADA OTTAWA (ONTARIO) BIOCHEMISTRY LAB
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N-p-Bromobenzoyl-exo-2,3-aziridinobicyclo2,2,1heptane, BrC6H4CONC7H10, crystallizes in the monoclinic space group. The structure was determined by the heavy-atom method using three-dimensional diffractometer data. The three bond distances in the bicyclo2,2,1 heptane system, C1-C2, C2-C3-C4 with values of 1.497, 1.491 and 1.512 A respectively, are shorter than the unstrained C-C single-bond distance. The bond angle C1-C7-C4 in the same heptane system with a value of 95.4 deg is highly strained.
- Atomic and Molecular Physics and Spectroscopy