Accession Number:

AD0754501

Title:

Crystal and Molecular Structure of N-p-Bromobenzoyl-exo-2,3-aziridinobicyclo(2,2,1)heptane,

Descriptive Note:

Corporate Author:

NATIONAL RESEARCH COUNCIL OF CANADA OTTAWA (ONTARIO) BIOCHEMISTRY LAB

Personal Author(s):

Report Date:

1971-05-21

Pagination or Media Count:

6.0

Abstract:

N-p-Bromobenzoyl-exo-2,3-aziridinobicyclo2,2,1heptane, BrC6H4CONC7H10, crystallizes in the monoclinic space group. The structure was determined by the heavy-atom method using three-dimensional diffractometer data. The three bond distances in the bicyclo2,2,1 heptane system, C1-C2, C2-C3-C4 with values of 1.497, 1.491 and 1.512 A respectively, are shorter than the unstrained C-C single-bond distance. The bond angle C1-C7-C4 in the same heptane system with a value of 95.4 deg is highly strained.

Subject Categories:

  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE