Accession Number:

AD0754477

Title:

The Synthesis of 9-Vertex, Monocarbon, Metallocarboranes by Polyhedral Contraction.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Report Date:

1972-01-08

Pagination or Media Count:

23.0

Abstract:

The base degradation of orange pi-C5H5CoIIIpi-6,7-B10C2H12 has been found to effect a polyhedral contraction reaction to give pi-C5H5CoIII-pi-2-B7CH8-1. This reaction constitutes the first reported example of a small metallocarborane formed by the removal of a carbon atom and three boron atoms from the polyhedral framework of a larger metallocarborane. Author

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE