Synthetic Transformations of Resin Acids. IX. Certain Derivatives of 12-Br-Dehydroabietic Acid,
FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO
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The authors attempted to produce anologs of gibberellins - potential plant growth regulators - from 12-Br-dehydroabietic acid. As a result of the synthetic transformation of 12-Br-dehydroabietic acid, 12-Br-6,7-diketomethyl dehydroabietate, 6 Br-1,2,3,4,10,11-hexadehydrofluorenol-9 and 1-carboxy-1, 11-dimethyl-7-isopropyl-6-Br-1,2,3,4,10,11-hexadehydrofluorenone-9, were obtained. By the condensation of 12-Br-6,7-diketomethyl dehydroabietate with o-phenylene diamine, the corresponding azine was obtained.
- Organic Chemistry