Accession Number:

AD0752202

Title:

The Synthesis and Chemistry of Fluorine-Containing Benezenediazooxides.

Descriptive Note:

Technical rept.,

Corporate Author:

AIR FORCE MATERIALS LAB WRIGHT-PATTERSON AFB OHIO

Personal Author(s):

• Spence,J. W.

Report Date:

1971-12-01

Pagination or Media Count:

61.0

Abstract:

The report covers the synthesis of fluorine-containing benezenediazooxides. Compounds of particular interest are tetrafluoro-ortho- and para-benezenediazooxides. Tetrafluoro-ortho- and para-benezenediazooxides were synthesized and characterized by infrared and nuclear magnetic resonance. Triphenylphosphine, beta-naphthol, and N, N-dimethylaniline were found to couple with the tetrafluoro-para-benezenediazooxide however, attempts to form derivatives of the tetrafluoro-ortho-benezenediazooxide were unsuccessful. Methoxytri-fluoro-1, 4-benezenediazooxide was synthesized from 2, 3, 5, 6-tetrafluoro-para-anisidine. The structure of this diazooxide and the mechanism of reaction are under investigation. Author

Descriptors:

• (*ORGANIC NITROGEN COMPOUNDS
• SYNTHESIS(CHEMISTRY))
• (*QUINONES
• CHEMICAL REACTIONS)
• HALOGENATED HYDROCARBONS
• FLUORINE COMPOUNDS
• KETONES
• DIENES
• NUCLEAR MAGNETIC RESONANCE
• MOLECULAR STRUCTURE
• INFRARED SPECTRA
• NITROBENZENES

Subject Categories:

• Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE