Accession Number:

AD0749741

Title:

On a Direct Relation between Nuclear Magnetic Resonance Chemical Shifts and Thermodynamic Excess Quantitities in Binary Systems with a Self-Associating Component,

Descriptive Note:

Corporate Author:

FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO

Report Date:

1972-08-17

Pagination or Media Count:

17.0

Abstract:

Based on the theory of the ideal associated mixture, a linear relation is derived between the chemical shift of protons capable of hydrogen bond formation and the ratio of the activity coefficients of the self-associating and the inert components of the mixture. Applicability and limits of the model are demonstrated using a series of alcohols in tetrachloromethane as examples. Author

Subject Categories:

  • Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE