Chemical Consequences of Unsaturation in Cyclic Organoboranes.
Final rept. 1 Mar 67-31 Oct 70,
CATHOLIC UNIV OF AMERICA WASHINGTON D C DEPT OF CHEMISTRY
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The physical and chemical consequences of the potential ppi-ppi effect in unsaturated, cyclic organoboranes have been studied. The first phase of research was devoted to the synthesis of the requisite cyclic ring systems three-membered borirene, four-membered cationic borete, five-membered borole, six-membered borabenzene, and seven-membered borepin, fully carbon conjugated rings. The second phase dealt with employing physical methods to assess the extent of carbon-boron conjugation. Author
- Organic Chemistry