On the Determination of the Individual Exchange Current Densities in Dual Consecutive Charge Transfer Reactions.
Research and development technical rept.,
ARMY ELECTRONICS COMMAND FORT MONMOUTH N J
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A method is described to measure the individual exchange current densities in redox electrode reactions of the type Sr S0 2e- in which the two electrons are exchanged in consecutive charge-transfer steps whose rates are too fast for steady-state polarization measurements to be applicable. This method consists of combining the values of the Tafel line intercepts obtained in galvanostatic measurements of the potential transients with determinations of d etadi in the vicinity of the equilibrium potential. Author
- Physical Chemistry