Accession Number:

AD0745355

Title:

Transition-Metal and Carborane Derivatives Obtained from B18H22.

Descriptive Note:

Technical rept.,

Corporate Author:

INDIANA UNIV BLOOMINGTON DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1972-06-01

Pagination or Media Count:

33.0

Abstract:

Reaction of n- or i-B18H202- with a variety of phosphine and carbonyl substituted complexes of cobalt, rhodium, nickel, palladium and platinum produced new metal-borane complexes of the general type, B18H20Metalligandn. Cyclohexyl isocyanide reacts with i-B18H22 to form the carborane, B18H20CNH2C6H11. A nonpolar complex B18H20 pyridine2 has been obtained by the reaction of pyridine with n-B18H22. Author

Subject Categories:

  • Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE