Transition-Metal and Carborane Derivatives Obtained from B18H22.
INDIANA UNIV BLOOMINGTON DEPT OF CHEMISTRY
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Reaction of n- or i-B18H202- with a variety of phosphine and carbonyl substituted complexes of cobalt, rhodium, nickel, palladium and platinum produced new metal-borane complexes of the general type, B18H20Metalligandn. Cyclohexyl isocyanide reacts with i-B18H22 to form the carborane, B18H20CNH2C6H11. A nonpolar complex B18H20 pyridine2 has been obtained by the reaction of pyridine with n-B18H22. Author
- Inorganic Chemistry