Accession Number:

AD0744591

Title:

A Calorimetric Study of Phenol-Pyridine Complexes in Carbon Tetrachloride Solution,

Descriptive Note:

Corporate Author:

ROYAL MILITARY COLL OF CANADA KINGSTON (ONTARIO)

Personal Author(s):

• Barton,S. S.
• Kraft,J. P.
• Owens,T. R.
• Skinner,L. J.

Report Date:

1971-09-13

Pagination or Media Count:

4.0

Abstract:

The heats of reaction between a dilute solution of phenol in carbon tetrachloride and pyridine and the monomethyl-pyridines have been measured in an ice-calorimeter. The calculated enthalpy change per mol of hydrogen-bonded adduct formed appears to be insensitive to basicity and the position of the methyl group. Author

Descriptors:

• (*PYRIDINES
• *COMPLEX COMPOUNDS)
• (*PHENOLS
• COMPLEX COMPOUNDS)
• CALORIMETRY
• STEREOCHEMISTRY
• CARBON TETRACHLORIDE
• ORGANIC SOLVENTS
• CANADA

Subject Categories:

• Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE