Accession Number:

AD0739718

Title:

The Thermal Rearrangement of Pi-Cyclopentadienyl-Pi-dicarbollyl Derivatives of Cobalt.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s):

• Kaloustian,Moses K.
• Wiersema,Richard J.
• Hawthorne,M. Frederick

Report Date:

1972-03-14

Pagination or Media Count:

42.0

Abstract:

Vapor-phase rearrangement of Pi-C5H5CoPi-3-1,2-R2-B9C2H9, RH, CH3, R2CH23 at 400-700C produces all possible isomers formed by migration of the cage carbon atoms over the polyhedral surface. The separations and physical properties of the various isomers are discussed. Author

Descriptors:

• *BORON COMPOUNDS
• *COBALT COMPOUNDS
• *COMPLEX COMPOUNDS
• CHEMICAL REACTIONS
• DIENES
• ORGANOMETALLIC COMPOUNDS
• MOLECULAR ISOMERISM
• CHROMATOGRAPHIC ANALYSIS
• ELECTROCHEMISTRY
• NUCLEAR MAGNETIC RESONANCE
• ULTRAVIOLET SPECTRA
• VISIBLE SPECTRA

Subject Categories:

• Inorganic Chemistry
• Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE