X-Ray Spectra of Iron Phosphonate.
EDGEWOOD ARSENAL MD
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The X-ray powder diffraction data were obtained for three iron phosphonate compounds FeMMP3, FeEEP3, and FeIMP3. The X-ray patterns for these compounds were similar to the X-ray patterns of other trivalent transition metal ions with phosphonate and phosphinate linkages. A very strong peak observed in the X-ray spectra of these compounds corresponds to the d spacing which is related to the repeat distance between metal atoms. The d spacing was observed to increase from FeMMP3 - FeEEP3 - FeIMP3, and this was attributed to the alkoxy group size occupying the open space in the framework of these compounds. Author
- Inorganic Chemistry
- Physical Chemistry