Accession Number:

AD0735926

Title:

Sigmi-Bonded Complexes of Substituted Phospha- and Arsacarboranes and Their Pi-Ollyl Derivatives.

Descriptive Note:

Technical rept.,

Corporate Author:

INDIANA UNIV BLOOMINGTON DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1972-01-01

Pagination or Media Count:

28.0

Abstract:

The photochemical reaction of 1,7-B9H9CHE2Fe2- E P or As with group VI metal carbonyls lead to the formation of complexes with the general formula, 1,7-B9H9CHEMCO52Fe2-. It is proposed that each heteroatom carborane ligand is pi - bonded to the iron atom and sigma - bonded through either the phosphorus or arsenic atom to a group VI metal carbonyl. The preparation and characterization of a neutral phosphacarborane sigma - complex is described. Author

Subject Categories:

  • Inorganic Chemistry
  • Radiation and Nuclear Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE