Accession Number:

AD0735926

Title:

Sigmi-Bonded Complexes of Substituted Phospha- and Arsacarboranes and Their Pi-Ollyl Derivatives.

Descriptive Note:

Technical rept.,

Corporate Author:

INDIANA UNIV BLOOMINGTON DEPT OF CHEMISTRY

Personal Author(s):

• Todd,L. J.
• Beer,D. C.

Report Date:

1972-01-01

Pagination or Media Count:

28.0

Abstract:

The photochemical reaction of 1,7-B9H9CHE2Fe2- E P or As with group VI metal carbonyls lead to the formation of complexes with the general formula, 1,7-B9H9CHEMCO52Fe2-. It is proposed that each heteroatom carborane ligand is pi - bonded to the iron atom and sigma - bonded through either the phosphorus or arsenic atom to a group VI metal carbonyl. The preparation and characterization of a neutral phosphacarborane sigma - complex is described. Author

Descriptors:

• (*BORON COMPOUNDS
• *COMPLEX COMPOUNDS)
• (*PHOTOCHEMICAL REACTIONS
• *BORATES)
• (*METAL CARBONYLS
• PHOTOCHEMICAL REACTIONS)
• IRON COMPOUNDS
• PHOSPHORUS COMPOUNDS
• ARSENIC
• SYNTHESIS(CHEMISTRY)
• MASS SPECTRA
• INFRARED SPECTRA

Subject Categories:

• Inorganic Chemistry
• Radiation and Nuclear Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE