The Electronic Absorption Spectrum of 3,3-Chloromethyl-D3-Diazirine.
ARMY MISSILE COMMAND REDSTONE ARSENAL ALA PHYSICAL SCIENCES DIRECTORATE
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The high resolution electronic absorption spectrum of 3,3-chloromethyl-d3-diazirines is presented. A vibrational analysis is given for the allowed singlet-singlet pi from n system with its 0-0 band at 28 312cm. Fundamental frequencies are compared with those of the normal molecule. The symmetrical NN stretching vibration with a frequency of 1446cm is the most prominent feature observed for the system. Evidence is also presented for another electronic system 140cm to the red of the singlet-singlet system. Author
- Organic Chemistry
- Atomic and Molecular Physics and Spectroscopy