Accession Number:

AD0729517

Title:

Reaction of D-ribo-Hexos-3-ulose and of 1,2:5,6-Di-O-Isopropylidene-alpha-D-ribo-hexo-1,4-furanos-3-ulose 3-hydrate with Methanol-Hydrogen Chloride. A preparation of D-ribo-3-Hexulose,

Descriptive Note:

Corporate Author:

SVENSKA TRAFORSKNINGSINSTITUTET STOCKHOLM

Personal Author(s):

Report Date:

1970-06-12

Pagination or Media Count:

11.0

Abstract:

The reaction of D-ribo-hexos-3-ulose with methanol-hydrogen chloride yielded as major products methyl methyl beta-D-ribo-hexo-1,4-furanosid-beta-D-3-ulo-3,6-furanoside, and methyl methyl alpha-D-ribo-hexo-1,4-furanosid-beta-D-3-ulo-3,6-furanoside. Similar treatment of 1,25,6-di-O-isopropylidene-alpha-D-ribo-hexo-1,4-furanos-3-ulose 3-hydrate afforded the same products together with methyl 1,2-O-isopropylidene-alpha-D-ribo-hexo-1,4-furanos-beta-D-3-ulo-3,6-furanoside. Author

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE