Accession Number:

AD0728439

Title:

Novel Cyanocarbon Derivatives.

Descriptive Note:

Technical rept. 1 Aug 70-31 Jul 71,

Corporate Author:

GEORGIA UNIV ATHENS DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1971-08-01

Pagination or Media Count:

15.0

Abstract:

The report discusses Preparation of dicyanomethylenecarbene andor metal complexes thereof Preparation of tetracyanoallene Reactions of hexacyanobutadiene and related compounds. Of particular interest was the isolation and characterization of the complex C5H52Fe2CO3CCCN2, the first known derivative of dicyanomethylenecarbene. In addition, most reactions of the metal carbonyl anions NaMCO3C5H5MMo and W, NaMnCO5, and NaFeCO2C5H5 with the polycyanovinyl chlorides NC2CCHCl, NC2CCCNCl, and NC2CCCl2 were found to give fair to good yields of the corresponding polycyanovinyl transition metal derivatives. Author

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE