Research in NF Compounds
Semiannual technical rept. 1 Dec 1968-31 May 1969
AEROJET-GENERAL CORP EL MONTE CA ENVIRONMENTAL SYSTEMS DIV
Pagination or Media Count:
The following phases of the program were completed and the work was assembled in the form of manuscripts 1 Substituent Constants of Difluoraminoaklyl and Gem-bisdifluoraminoalkyl Groups, 2 Direct Fluorination of Secondary Nitronate Salts, and 3 Michael Reactions of 2-Fluoro-2,2- dinitroethanol and 2,2-Dinitropropanol with Olefinic and Acetylenic Acceptors. Nmr spectra of 2-difluoramino-2-phenylazopropane in sulfuric acid indicated initial protonation of the azo group followed by slow hydrolysis to give acetone, ammonium ion and nitrosobenzene. Spectra in fluosulfonic acid showed that a different reaction took place, possibly 1,2-shift of the phenylazo group.
- Organic Chemistry