Accession Number:

AD0722023

Title:

Molecular Adsorption Cross Section and Orientation of Tetraphenylporphine and Its Copper Derivative at Mercury and Air Interfaces.

Descriptive Note:

Research and development rept.,

Corporate Author:

NAVAL SHIP RESEARCH AND DEVELOPMENT LAB ANNAPOLIS MD

Personal Author(s):

Report Date:

1971-04-01

Pagination or Media Count:

18.0

Abstract:

The molecular orientation, adsorption cross section, and structure of porphine, tetraphenyl-, copper tetraphenyl-, and four-chloromesotetraphenylporphine in benzene solution at a mercury and air interface have been determined experimentally from interfacial and surface tension measurements. The data fit well to Shereshefskys equations, and the results are compatible with those obtained from X-ray diffraction measurements on the solid phase. Author

Subject Categories:

  • Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE