Inorganic Mass Spectrometry and Thermochemistry Related to Fuels, Structural Materials and Polymers.
Final scientific rept. 1 May-30 Sep 70,
SUSSEX UNIV BRIGHTON (ENGLAND) CHEMICAL LAB
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The report is divided into four sections Photo-electron spectroscopy of dimethyl aminohaloboranes 11B nuclear magnetic resonance data for the boron trihalides and mixed trihalides Mass spectrometric studies on compounds Me4M and Me3M-M1Me3 M and M1C, Si, Ge, Sn, and Pb and Metal-metal bond dissociation energies, raman and infrared spectra for the series pi-C5H5CO3M1M2Me3M1-Cr, Mo, or W M2Ge or Sn. The compounds investigated are simple derivatives of boron, carbon, and silicon and the other Group IV elements. Increased knowledge of basic thermodynamic parameters for such compounds is important in assessing the suitability of more complex compounds as fuels, structural materials, and inorganic polymers capable of withstanding exposure to high temperatures. Author
- Organic Chemistry