STUDIES IN STEREOCHEMISTRY.
Final rept. 1 Aug 68-31 Aug 70,
PRINCETON UNIV N J DEPT OF CHEMISTRY
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Brief summaries are presented on stereochemical research on the following topics Synthesis and configuration of phosphine oxides Hexachlorodisilane A novel reducing agent for organic oxides and sulfides Optical purity of phosphines by NMR Pseudorotation and the stereochemistry of displacement reactions Stereomutation of phosphine oxides by lithium aluminum hydride Optical rotatory power 2,3-Sigmatropic rearrangements and Energy barriers in pyramidal inversion process.
- Inorganic Chemistry