Accession Number:
AD0712540
Title:
SMALL CARBORANE-METALLOCENE ANALOGS. IRON pi-COMPLEXES CONTAINING THE NIDO-C2B4H6(-2)-AND CYCLO-C2B3H7(-2)-LIGANDS.
Descriptive Note:
Technical rept.,
Corporate Author:
VIRGINIA UNIV CHARLOTTESVILLE DEPT OF CHEMISTRY
Personal Author(s):
Report Date:
1970-10-01
Pagination or Media Count:
10.0
Abstract:
New carborane-transition metal pi-complexes involving the nido-C2B4H62- and cyclo-C2B3H72- ligands have been synthesized from iron pentacarbonyl and 2,3-dicarba-closo-hexaborane8 in a heated tube, and the structures have been assigned on the basis of boron-11 and proton nmr spectra, as well as infrared and mass spectroscopic evidence. Author
Descriptors:
Subject Categories:
- Inorganic Chemistry