SMALL CARBORANE-METALLOCENE ANALOGS. IRON pi-COMPLEXES CONTAINING THE NIDO-C2B4H6(-2)-AND CYCLO-C2B3H7(-2)-LIGANDS.
VIRGINIA UNIV CHARLOTTESVILLE DEPT OF CHEMISTRY
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New carborane-transition metal pi-complexes involving the nido-C2B4H62- and cyclo-C2B3H72- ligands have been synthesized from iron pentacarbonyl and 2,3-dicarba-closo-hexaborane8 in a heated tube, and the structures have been assigned on the basis of boron-11 and proton nmr spectra, as well as infrared and mass spectroscopic evidence. Author
- Inorganic Chemistry