Accession Number:

AD0712540

Title:

SMALL CARBORANE-METALLOCENE ANALOGS. IRON pi-COMPLEXES CONTAINING THE NIDO-C2B4H6(-2)-AND CYCLO-C2B3H7(-2)-LIGANDS.

Descriptive Note:

Technical rept.,

Corporate Author:

VIRGINIA UNIV CHARLOTTESVILLE DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1970-10-01

Pagination or Media Count:

10.0

Abstract:

New carborane-transition metal pi-complexes involving the nido-C2B4H62- and cyclo-C2B3H72- ligands have been synthesized from iron pentacarbonyl and 2,3-dicarba-closo-hexaborane8 in a heated tube, and the structures have been assigned on the basis of boron-11 and proton nmr spectra, as well as infrared and mass spectroscopic evidence. Author

Subject Categories:

  • Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE