Accession Number:

AD0712498

Title:

THE CHEMISTRY OF BIS(pi-(3)-1,2-DICARBOLLYL) METALATES. PROTONATION AND B-SUBSTITUTION.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Report Date:

1970-09-14

Pagination or Media Count:

39.0

Abstract:

The sandwich bonded bispi-3-1,3-dicarbollylFeII-2 ion is protonated in strongly acidic media to form what may prove to be the analog of protonated ferrocene. This species readily reacts with dialkyl-sulfides to form B-substituted bisdicarbollylironII and -III species. Analogous reactions have been carried out employing bisdicarbollyliron III and -cobaltIII anions. The preparation, characterization and structures of these complexes are discussed. Author

Subject Categories:

  • Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE