Accession Number:

AD0712498

Title:

THE CHEMISTRY OF BIS(pi-(3)-1,2-DICARBOLLYL) METALATES. PROTONATION AND B-SUBSTITUTION.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s):

• Hawthorne,M. Frederick
• Warren,Leslie F. , Jr.
• Callahan,Kenneth P.
• Travers,Neill F.

Report Date:

1970-09-14

Pagination or Media Count:

39.0

Abstract:

The sandwich bonded bispi-3-1,3-dicarbollylFeII-2 ion is protonated in strongly acidic media to form what may prove to be the analog of protonated ferrocene. This species readily reacts with dialkyl-sulfides to form B-substituted bisdicarbollylironII and -III species. Analogous reactions have been carried out employing bisdicarbollyliron III and -cobaltIII anions. The preparation, characterization and structures of these complexes are discussed. Author

Descriptors:

• (*BORATES
• *COMPLEX COMPOUNDS)
• (*IRON COMPOUNDS
• COMPLEX COMPOUNDS)
• SYNTHESIS(CHEMISTRY)
• IONS
• MOLECULAR STRUCTURE
• COBALT COMPOUNDS
• NUCLEAR MAGNETIC RESONANCE

Subject Categories:

• Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE