Accession Number:

AD0711593

Title:

THE FORMATION OF NOVEL COBALT-CARBORANE COMPLEXES INVOLVING LIGANDS PRODUCED BY REDUCTION OF 1,6-C2B6H8.

Descriptive Note:

Technical rept.,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Report Date:

1970-08-31

Pagination or Media Count:

14.0

Abstract:

The carborane, 1,6-C2B6H8, was reduced with sodium amalgam or sodium naphthalide which produced the apparent C2B6H8-2 ion. Treatment of this ion with CoCl2 produced the C2B6H82CoIII- ion. Treatment of a 15 mixture of C2B6H8-2 and C5H5- ions with CoCl2 produced the red C2B6H8CoC5H5 and the green C2B6H8Co2C5H52 mixed complexes. Author

Subject Categories:

  • Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE