THE FORMATION OF NOVEL COBALT-CARBORANE COMPLEXES INVOLVING LIGANDS PRODUCED BY REDUCTION OF 1,6-C2B6H8.
CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY
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The carborane, 1,6-C2B6H8, was reduced with sodium amalgam or sodium naphthalide which produced the apparent C2B6H8-2 ion. Treatment of this ion with CoCl2 produced the C2B6H82CoIII- ion. Treatment of a 15 mixture of C2B6H8-2 and C5H5- ions with CoCl2 produced the red C2B6H8CoC5H5 and the green C2B6H8Co2C5H52 mixed complexes. Author
- Inorganic Chemistry